I have been battling this one and am annoyed to find that support for FTPS was not included in Dreamweaver until CS5.5 was presented on April 12, 2011. Glad to say I was able to find a note on it.
Resources:
http://helpx.adobe.com/dreamweaver/using/connect-remote-server.html
http://en.wikipedia.org/wiki/Adobe_Creative_Suite#Creative_Suite_5.5
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